Plastic
permeates our lives. Objects made from
plastic materials are seemingly in our hands from dawn to dusk. Toothbrushes, drinking cups, components of
the vehicles that take us to work or school, bank cards that pay for lunch, soles
of gym shoes, water bottles. The list
could go on and on.
Plastic is ever
so versatile, lending to its adoption for so many applications. It can be shaped into balls, rolled into
sheets, strung into long fibers, poured and then hardened in molds, or any
number of other processes that squash and press it into the right shape and
feel. Plastic is durable while still
retaining flexibility. Strength is not
compromised even under extreme environmental temperature.
Versatility is
joined to economy and efficiency. An
entire manufacturing industry has developed to provide original equipment
makers with the plastic parts that will give final goods full
functionality. Injection molding, thermoforming,
blow molding, rotational molding, film blowing, and extrusion are just a few of
the processes that make plastic into functional objects. All can be scaled to high volumes that put
plastic among the most cost-effective materials available.
Downside of Versatility
Yet plastic has
downsides. The negatives may not be as numerous as the many uses, but the
consequences are dire. We list below a
few of the problems created by plastics.
Air Pollution -
Plastics production processes expose workers to toxic chemicals. A similar exposure to airborne toxins can occur
when plastics are incinerated at waste disposal facilities. Most plastics are based on the carbon atom
that is linked to hydrogen oxygen, nitrogen, chlorine or sulfur. The raw material formation begins with
separation of hydrocarbon chemicals from natural gas, crude oil or coal into
pure streams of chemicals called monomers.
The monomers are then chemically bonded into chains called polymers or
plastics.
There are numerous
hazardous substances used in making plastics, including solvents, initiators,
catalysts and other polymerization additives.
Solvents such as methanol or heptanes may be toxic and flammable. Used as initiators, potassium persulfate and
benzoyl peroxide can cause respiratory problems.
Food Chain Toxicity -
There are thousands of additives used in plastics production: peroxide to speed up polymerization,
brominated flame retardants, phthalates and lead compounds for heat
stabilization.
Brominated flame
retardants are much like polychlorindated bisphenyles, otherwise known as
PCBs. PCBs accumulate in the fat tissues
of aquatic animals such as fish, leading to neurotoxic effects and altered
thyroid functions. Other aquatic animals
get hit by phthalate plasticizers. These
are estrogenic compounds that can disrupt endocrine function and reproductive
systems. Algae, invertebrates and other
micro-organisms are particularly vulnerable to phthalates.
Leaching -
Additives are not usually chemically bound to the plastic structure and
they represent a substantial amount of all the chemical substances in plastics. For example, PVC may contain more than 40% by
weight of plasticizers such as phthalates.
These hazardous additive substances can be released or leached at all
phases of plastic life cycle.
Leachable
compounds can be found in all plastics except polypropylene. Printed polyethylene and polyvinyl chloride
type plastics have the highest leaching rates, while polyethylene terephthalate
type plastics have the lowest leaching potential. As might be expected plastics left in
turbulent water experience faster leaching rates. Exposure to ultraviolet radiation and salt
water also accelerate leaching rates.
It is not just
the additives in plastics that can leach into water or soil and eventually find
their way into the food chain. Polymers
with their large molecular size are usually considered to be biochemically
inert and harmless to the environment.
However, monomers used in plastic are another story. Bisphenol or BPA disrupts endocrine
function. Styrene and vinyl chloride are
carcinogenic and mutagenic.
Microplastic
- As plastic waste moves about the land and sea, breaking into smaller pieces
it becomes microplastic, which is defined by the NOAA as plastic bits less than
five millimeters in diameter. Not much
is known as yet about microplastic and what impact it might have on animal
physiology or food crop growth. One of
the few studies completed to date found that earthworms exposed to microplastic
in soil have increased gut inflammation, slower growth and high mortality.
What is clearer
is that it is widespread. A study by the
Galway-Mayo Institute of Technology in Dublin found microplastic in tap water
and well water in Ireland. Then there
are the notorious microplastic collections in both the Pacific and Atlantic
Oceans.
Exemplary of the
ocean collections of microplastic and chemical sludge is the Great Pacific
Garbage Patch in the North Pacific Ocean.
It was discovered in the late 1980s by the U.S. National Oceanic and
Atmospheric Administration (NOAA).
Discarded fishing gear represents about 60% of the gigantic mass of
plastic marine debris. Another
significant component is micro-pellets used in abrasive clearers. Most of the contents are suspended beneath
the surface of the ocean and some particles are so tiny they are invisible to
the naked eye. The microplastic soup is
simply floating in the ocean slowly making its way into the digestive systems
of the tuna, salmon, ahi ahi, and sea bass investors are ordering for lunch.
Entanglements - It
takes about two to four weeks for a paper towel to degrade. An apple core will be around as long as two
months before Mother Nature can process it back into the most basic
elements. A plastic bottle on the other
hand will be around for as long as one hundred years. Real longevity is represented by monofilament
fishing line that can last more than six centuries. For six hundred years the turtles, whales,
dolphins, sharks, and crabs will have to dodge and dive around monofilament fishing
gear left behind by fisherman. Abandoned
fishing gear trap, maim and kill hundreds of marine animals daily.
In 2013, the
Food and Agriculture Organization and the United Nations Environmental Program
estimated that 640,000 tons of abandoned fishing gear are floating around the
world’s oceans. The building gear retards the marine food chain by impeding
movement needed for reproduction cycles and reducing breeding age population.
Plastic Legacy
The first
plastic was made in the late 1800s by Alexander Parkes, a metallurgist and
inventor in England. Then in 1907, Leo
Baekland made the first synthetic polymer from phenol and formalydehyde. Called Bakelite after Baekland, it was the
first commercially successful plastic.
In the 110 years since, six different plastics have been developed: polyethylene terephthalate (PET),
high-density polyethylene (HDPE), polyvinyl chloride (PVC), low-density
polyethylene (LDPE), polypropylene (PP), polystryrene (PS), and bisphenol A or
S (BPA and BPS).
The University
of California at Santa Barbara studies ocean pollution. Of the 9.1 billion tons of plastic produced
since 1950, as much as 7 billion tons are no longer in use. Of this amount, only 9% is estimated to have
been recycled and another 12% incinerated.
That leaves about 79% or 5.5 billion tons of plastic waste somewhere in
the world. Some plastic is still in use
in our homes and offices. Unfortunately,
probably most of the plastic made so far is at large in the ocean or on land slowly
devolving into microplastic and seeping into the food chain.
The next few posts will focus on companies attempting
to deal with the plastic refuse in our world.
Neither the author of the Small Cap Strategist web
log, Crystal Equity Research nor its affiliates have a beneficial interest in
the companies mentioned herein.
1 comment:
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